Pd(II) ion fixed on sulfonated polystyrene-type resin catalysts for the oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone with hydrogen peroxide.
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منابع مشابه
Sulfric acid as Effective Catalyst for the Oxidation of 2-Methyl Naphthalene by hydrogen peroxide
The oxidation of 2-Methylnaphthalene (2-MN) was carried out in actic acid with 30%H2O2. 2-Methyl-1,4Naphthoquinone (2-MNQ) was obtained in a yield of 81.3% when sulfric acid used as catalyst. The aromatic substituted pathway is speculated as the dominated oxidation pathway with a higher conversion than the epoxidation one due to the activity of CH3CO3H2 + formed by actic acid and H+ supplied fr...
متن کاملStudies on the photochemistry of 2-methyl-1,4-naphthoquinone.
It has been known since the isolation of the vitamins K that derivatives of 2-methyl-1,4-naphthoquinone (MN&) are unstable to light (l-5). However, the exact nature of the chemical change is still under discussion (6, 7). An interesting observation by MacCorquodale and coworkers (3) that the vitamin is quite stable as it exists in crude extracts, only becoming labile after a fair degree of puri...
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Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well...
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T HE practice of chemistry is concerned very largely with the carrying out of chemical reactions whereby new substances are produced from old. The substances entering into the reaction are'known as reagents, and the substances produced as products. One of the factors in chemical reactions which is subject to human control and manipulation is summarized in the Law of Mass Action. This law, in si...
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The vanadate anion in the presence of pyrazine-2-carboxylic acid (PCA) was found to effectively catalyze the oxidation of isopropanol to acetone with hydrogen peroxide. The electronic spectra of solutions and the kinetics of oxidation were studied. The conclusion was drawn that the rate-determining stage of the reaction was the decomposition of the vanadium(V) diperoxo complex with PCA, and the...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1986
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.34.445